This is really a case for the Psychic mechanic... not enough information to know for sure. first guess is trapped air in the system, second is improperly installed thermostat (it is directional), third is something is trapped in the system (plastic cap?).. ¿If it was over heating before you replaced the thermostat.? would be headgasket, waterpump,or catalytic converter, or clogged radiator.. . the Psychic mechanic is going to go out on a limb here and say it is a ford v-6, the head gasket is blown due in part to a clogged catalytic converter.